The Hydrothermal Stability of Paper-Like Ceramic Fiber and Conventional Honeycomb-Type Cordierite Substrates Washcoated with Cu-MFI and V2O5/TiO2 Catalysts for the Selective Reduction of NOx by NH3

A paper-like ceramic fiber was employed as a monolith substrate for removing NO by NH₃. The stronger hydrothermal stability of the ceramic fiber washcoated with V₂O₅/TiO₂ was observed by the pre-calcination of the substrate, mainly due to the well dispersed AlPO₄ formed on the substrate surface improving the washcoating of the catalysts and moderating the phase transformation of TiO₂ from anatase to rutile.     

CO oxidation from syngas (CO and H<Subscript>2</Subscript>) using nanoporous Pt/Al<Subscript>2</Subscript>O<Subscript>3</Subscript> catalyst

The concept of “waste-to-wealth” is spreading awareness to prevent global warming and recycle the restrictive resources. To contribute towards sustainable development, hydrogen energy is obtained from syngas (CO and H₂) generated from waste gasification, followed by CO oxidation and CO₂ removal. In H₂ generation, it is key to produce more purified H₂ from syngas using heterogeneous catalysts. In this respect, we prepared Pt/Al₂O₃ catalyst with nanoporous structure using precipitation method, and compared its catalytic activity with commercial alumina (Degussa). Based on the results of XRD and TEM, it was found that metal particles did not aggregate on the alumina surface and showed high dispersion. Optimum condition for CO conversion was 1.5 wt% Pt loaded on Al₂O₃ support, and pure hydrogen was obtained after removal of CO₂ gas.     

Nanogap Array Fabrication Using Doubly Clamped Freestanding Silicon Nanowires and Angle Evaporations

We present a simple semiconductor process to fabricate nanogap arrays for application in molecular electronics and nano‐bio electronics using a combination of freestanding silicon nanowires and angle evaporation. The gap distance is modulated using the height of the silicon dioxide, the width of the Si nanowires, and the evaporation angle. In addition, we fabricate and apply the nanogap arrays in single‐electron transistors using DNA‐linked Au nanoparticles for the detection of DNA hybridization.     

Using the condenser effluent from a nuclear power plant for Ocean Thermal Energy Conversion (OTEC)

There has been increasing interest in clean energy over past few years. Ocean Thermal Energy Conversion (OTEC) power plants have been examined as a viable option for supplying clean energy. This paper evaluated the thermodynamic performance of the OTEC power system. Computer simulation programs were developed under the same conditions but with various working fluids for a closed system, a regeneration system, an open system, a Kalina system, and a hybrid system. The results showed that the regeneration system using R125 showed a 0.17 to 1.56% increase in system efficiency. Moreover, the system can generate electricity when the difference in temperature between the warm and cold seawater inlet temperatures is greater than 15 °C. In addition, the system efficiency of OTEC power plants using the condenser effluent from a nuclear power plant instead of surface water was increased by approximately 2%.     

Synthesis of chiral stationary phase via surface‐initiated atom transfer radical polymerization of vinylated cellulose 3,5‐dimethylphenylcarbamate

A polysaccharide‐immobilized chiral stationary phase (CSP) was prepared by the surface‐initiated atom transfer radical polymerization (SI‐ATRP), in pyridine, of cellulose 2,3‐bis(3,5‐dimethylphenylcarbamate), having a polymerizable vinyl group, on the surface of SiO₂ support. The successful preparation of the CSP was confirmed via Fourier transform infrared spectroscopy, field‐emission scanning electron microscopy, X‐ray photoelectron spectroscopy, elemental analysis and thermal analysis. The chiral recognition ability of the prepared CSP was evaluated with high‐performance liquid chromatography using 10 racemates with various mobile phases of hexane/alcohol, hexane/tetrahydrofuran and hexane/chloroform. As a result, this CSP prepared using SI‐ATRP can be used in tetrahydrofuran and chloroform solutions as eluents. Copyright © 2011 Society of Chemical Industry     

Distributed Borrowing Addressing Scheme for ZigBee/IEEE 802.15.4 Wireless Sensor Networks

This paper proposes a distributed borrowing addressing (DIBA) scheme to solve problems of failure in address assignments resulting from limited tree depth and width when the distributed address assignment mechanism is used in a ZigBee/IEEE 802.15.4 wireless sensor network. DIBA is a method of borrowing addresses from neighbor nodes for newly entering nodes and assigning the borrowed addresses. Its network or sensing coverage can increase with almost the same overhead as the existing method. DIBA is a simple and lightweight means of addressing and routing, making it suitable for wireless sensor networks. Simulations showed that DIBA is a distributed addressing scheme with consistently excellent performance.     

Thermal,mechanical and rheological properties of poly (lactic acid)/epoxidized soybean oil blends

Summary  Poly(lactic acid) (PLA) was melt blended with epoxidized soybean oil (ESO) in an internal mixer and thermal, mechanical and rheological properties of the blends were investigated by means of differential scanning calorimetry, dynamic mechanical analysis, tensile test and small amplitude oscillatory shear rheometry. ESO lowered glass transition temperature and increased the ability of PLA to cold crystallization. The blend exhibited improved elongation-at-break along with a plastic deformation. The plasticization effect by ESO was also manifested by the lowering of dynamic storage modulus and viscosity in the melt state of the blends compared with neat PLA.